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The data cover the period from June 2011 to March 2016. Sampling was weekly from June 2011 to December 2011 and then  fortnightly from January 2012. Data for the whole period are presented for major anions and cations, pH, conductivity, alkalinity and in-situ measurements such as water temperature and stream flow. From June 2011 to March 2013 data are also presented for a range of metals. Data are presented for the whole period for six stream locations and one rainfall site. Data are also for presented for two streams, Nant Iago and Tanllwyth and one cloud site for the period from June 2011 to July 2012. \n\nStream samples were taken using a grab technique. Rain samples were collected using bulk precipitation collectors. Cloud samples were collected using a Centre of Ecology and Hydrology (CEH) Edinburgh pattern lidded harp type passive collector. This data presented  follow on from the hydrochemical data presented in the dataset Plynlimon research catchment hydrochemistry (44095e17-43b0-45d4-a781-aab4f72da025)\nFieldwork was carried out by CEH members of staff trained in the fieldwork techniques required. Chemical analysis was carried out by qualified CEH chemists at laboratories at CEH Lancaster and CEH Bangor.\n\nThe Plynlimon research catchments lie within the headwaters of the River Severn and the River Wye in the uplands of mid-Wales. Intensive and long-term monitoring within the catchments underpins a wealth of hydrological and hydro-chemical research. Monitoring is funded by the Centre for Ecology & Hydrology, and is ongoing since 1968.","distributionFormats":[{"name":"Comma-separated values (CSV)","type":"text/csv","version":"unknown"}],"distributorContacts":[{"organisationName":"NERC EDS Environmental Information Data Centre","organisationIdentifier":"https://ror.org/04xw4m193","role":"distributor","email":"info@eidc.ac.uk"}],"id":"794c609b-da62-4a42-a4c1-267219865bb1","incomingCitationCount":1,"incomingCitations":[{"description":"Knapp, J.L.A., Neal, C., Schlumpf, A., Neal, M., & Kirchner, J.W. (2019). New water fractions and transit time distributions at Plynlimon, Wales, estimated from stable water isotopes in precipitation and streamflow. 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Stream samples were taken using a grab technique. Rain samples were collected using bulk precipitation collectors. Cloud samples were collected using a Centre of Ecology and Hydrology (CEH) Edinburgh pattern lidded harp type passive collector. \n\nUpon return to the CEH Bangor laboratories the cation samples were acidified with concentrated Nitric Acid (to 1 percent) to preserve the samples. Samples for anion and cation sample were then stored at 4 degrees Celsius until they could be transported to the Centralised Analytical Chemistry Group in CEH Lancaster for analysis. Results were reported back to CEH Bangor as Excel spreadsheets. These data were then imported into an Access database.\n\npH, conductivity and alkalinity analysis was carried out the CEH Bangor laboratories. Results were reported back as Excel spreadsheets. Field measurements and flow calculations were also added to these Excel spreadsheets. These data were then imported into the same Access database as the CEH Lancaster results.\nFor ingestion into the Environmental Information data was extracted from the Access database and converted into a comma separated value file.","metadataDate":"2026-06-29T16:42:41","notGEMINI":false,"onlineResources":[{"url":"https://data-package.ceh.ac.uk/data/794c609b-da62-4a42-a4c1-267219865bb1","name":"Download the data","description":"Download a copy of this data","function":"download","type":"OTHER"},{"url":"https://data-package.ceh.ac.uk/sd/794c609b-da62-4a42-a4c1-267219865bb1.zip","name":"Supporting information","description":"Supporting information available to assist in re-use of this dataset","function":"information","type":"OTHER"}],"pointsOfContact":[{"familyName":"Norris","givenName":"Dave","organisationName":"UK Centre for Ecology & 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