Bhardwaj, C.L.; Dodd, J.C.; Bachiller-Jareno, N.; Tindall, I.; Moore, R.
        
        Micro-organic herbicides data from rivers [LOIS]
         https://doi.org/10.5285/e28ffc01-880d-423f-acb6-879b9fd4603a
        
       
            Cite this dataset as: 
            
           
          Bhardwaj, C.L.; Dodd, J.C.; Bachiller-Jareno, N.; Tindall, I.; Moore, R. (2013). Micro-organic herbicides data from rivers [LOIS]. NERC Environmental Information Data Centre. https://doi.org/10.5285/e28ffc01-880d-423f-acb6-879b9fd4603a
             
             
            
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         By accessing or using this dataset, you agree to the terms of the relevant licence agreement(s). You will ensure that this dataset is cited in any publication that describes research in which the data have been used.
© UK Centre for Ecology & Hydrology
 This dataset is made available under the terms of the Open Government Licence  
 
          Micro-organic herbicide levels in river water for various sites within the Humber and Tweed catchments collected as part of the Land Ocean Interaction Study project (LOIS). The dataset contains data for Phenyl urea and Phenoxy acid herbicides, measured as 2,4-Dichlorophenoxyacetic acid, 4-(4-Chloro-O-tolyloxy) butyric acid, 4-Chloro-O-tolyloxyacetic acid, Chlorotoluron dissolved, Diuron dissolved, Isoproturon dissolved, Linuron dissolved, Mecoprop dissolved. Phenyl urea herbicide data is available for twelve sites in the Humber catchment within 1994 to 1995 and 1994 to 1997 and for three sites on the Tweed catchment within 1995. Phenoxy acid herbicide data is available for six sites (S1, U3, N4, W5 and O6) over the period December 1994 to September 1995, for 7 sites (S2, D7, A8, C9, D10, T11 and O12) over the period December 1994 to February 1997 and 3 sites (TW13, TW14 and TW15) over the period January 1995 to September 1995. Attempts were made to sample the sites at weekly intervals. However sampling was halted for short periods when it was not possible to process the samples quickly. Linuron dissolved was only measured from April 1994 - October 1994. Samples were collected in chromic acid-washed 1 litre glass bottles. Herbicide levels were concentrated before being measured using High Performance Liquid Chromatography for Phenyl urea herbicides and Gas Chromatography for Phenoxy acid herbicides. Until November 1994, analysis was completed by the York University and the Institute for Freshwater Ecology, Wareham, laboratories. From December 1994 onwards the samples were dispatched to the Institute for Hydrology, Wallingford, for extraction and analyses. 
          
         
           Publication date: 2013-07-01
          
         View numbers valid from 01 June 2023 Download numbers valid from 20 June 2024 (information prior to this was not collected)
           
          Format
Comma-separated values (CSV)
Spatial information
          Study area
         
         
          Spatial representation type
         
         
          Tabular (text)
         
        
          Spatial reference system
         
         
          OSGB 1936 / British National Grid
         
        Temporal information
          Temporal extent
         
         1993-09-07    to    1997-10-29
          
         Provenance & quality
         Phenyl urea herbicides were concentrated by using one of the following methods: solid phase extraction (SPE) using C18 (1gm, 6ml) (EC) (ISOLUTE) cartridges and eluting with ethyl acetate; as previous method except that the dried cartridge after loading was washed with 6ml of methanol: water:: 1:1 (to remove the impurities) before eluting the herbicides with methanol; liquid-liquid extraction with dichloromethane. Phenoxy acid herbicides were concentrated using liquid-liquid extraction with dichloromethane. Phenyl urea herbicides were measured by High Performance Liquid Chromatography (HPLC) with detection by a UV/VIS detector and phenoxy acid herbicides by Gas Chromatography (GC) with detection by a mass selective detector (GS-MS). One sample from each batch was randomly spiked with a mixed standard of urea and acid herbicides for comparison purposes. For all determinands certified grade standards of purity >99% were used. The laboratory at Wallingford takes part in WRC's AQUACHECK inter-laboratory harmonisation exercise for urea and acid herbicides. Data quality for both groups of herbicides is variable because of the nature of samples (Aire, Calder, Don and Trent were found to be highly polluted resulting in complex chromatograms), the level of herbicides present (mostly they are close to the detection limit) and difficulties in extraction especially in liquid-liquid extraction where they formed emulsions. A zip file of box-and-whisker plots are available for each determinand, showing the range of values (median, inter-quartile range, 1.5 * inter-quartile range, outliers) recorded at each site to enable prospective users to understand data quality.
        
       Licensing and constraints
 This dataset is made available under the terms of the Open Government Licence  
 
         Cite this dataset as: 
         
        Bhardwaj, C.L.; Dodd, J.C.; Bachiller-Jareno, N.; Tindall, I.; Moore, R. (2013). Micro-organic herbicides data from rivers [LOIS]. NERC Environmental Information Data Centre. https://doi.org/10.5285/e28ffc01-880d-423f-acb6-879b9fd4603a
          
          
         
        © UK Centre for Ecology & Hydrology
Related
This dataset is included in the following collections
The Land Ocean Interaction Study (LOIS) core monitoring data from river catchments
Supplemental information
          British Oceanographic Data Centre's webpages for information on and data from the coastal and marine aspects of the LOIS project.
         
        Correspondence/contact details
          UK Centre for Ecology & Hydrology
         
         
          Maclean Building, Benson Lane, Crowmarsh Gifford
Wallingford
Oxfordshire
OX10 8BB
UNITED KINGDOM
         
  enquiries@ceh.ac.uk
        Wallingford
Oxfordshire
OX10 8BB
UNITED KINGDOM
Authors
          Bhardwaj, C.L.
         
         
          Centre for Ecology & Hydrology
         
        
          Dodd, J.C.
         
         
          Centre for Ecology & Hydrology
         
        
          Bachiller-Jareno, N.
         
         
          Centre for Ecology & Hydrology
         
        
          Tindall, I.
         
         
          Centre for Ecology & Hydrology
         
        
          Moore, R.
         
         
          Centre for Ecology & Hydrology
         
        Other contacts
          Rights holder
         
         
           UK Centre for Ecology & Hydrology
          
         
          Custodian
         
         
            NERC EDS Environmental Information Data Centre
           
  info@eidc.ac.uk
          
          Publisher
         
         
            NERC Environmental Information Data Centre
           
  info@eidc.ac.uk
          Additional metadata
          Keywords
         
         2-4-Dichlorophenoxyacetic acid , 4-(4-Chloro-O-tolyloxy) butyric acid , 4-Chloro-O-tolyloxyacetic acid , Aire , Calder , Chlorotoluron , Derwent , Diuron , England  , herbicide  , Humber , Isoproturon , Land Ocean Interaction Study , Linuron , LOIS , Mecoprop , Nidd , Ouse , Phenoxy acid , Phenyl urea , Swale , Trent , water quality  , Water quality 
         
         
      